2. Mr. and Mrs. Smith
The break-up that shook Hollywood was the split between America’s sweethearts Brad Pitt and Jennifer Aniston. The pair, who had been married for five years, separated following the release of the 2005 film. Sources claim that Pitt had met and fallen for the seductive Angelina Jolie on the set of the movie. The pair were spotted by paparazzi meeting up in Kenya just one month after Aniston filed for divorce.
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