5. Ian Somerhalder and Nina Dobrev
Soon after they sizzled with on-screen chemistry in The Vampire Diaries, Ian Somerhalder and Nina Dobrev hooked up in the real life as well. However, while their love blossomed in the CW television drama, their relationship in the real world fizzled. They eventually broke up in 2013. Thankfully for their fans, the stars’ personal problems did not come in the way of their professional duties, and they continue to love each other in the drama.
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