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4. Adam Brody and Rachel Bilson – ‘The O.C.’

Teenage love had us all feening for our high school sweethearts while watching Adam Brody and Rachel Bilson interact on The O.C. It was their loving, innocent and adorable romance that had many of us convinced that these two were definitely hooking up after the director yelled “cut!” And it wasn’t long before their on-screen chemistry led to an off-screen romance. Although their real-life relationship didn’t last, the chemistry they portrayed on the series never faltered.

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